Search results for "Elektronu paramagnētiskā rezonanse"

showing 2 items of 2 documents

FOTOHROMĀ EFEKTA IZCELSME AR DZELZI AKTIVĒTĀ BĀRIJA MAGNIJA SILIKĀTĀ

2022

BaMgSiO4:Fe ir viens no visizteiksmīgākajiem neorganiskajiem fotohromiem materiāliem, tomēr fotohromā efekta izcelsme BaMgSiO4:Fe nav viennozīmīgi izskaidrota. Darbā ir sintezēti BaMgSiO4:Fe paraugi, un tie ir pētīti ar difūzās atstarošanās optiskās spektroskopijas un elektronu paramagnētiskās rezonanses (EPR) spektroskopijas metodēm. Darbā apspriesta fotohromā efekta izcelsme BaMgSiO4:Fe, kā arī noteikta optimālā Fe koncentrācija un sintēzes apstākļi efekta pastiprināšanai.

Fe [BaMgSiO4]Difūzās atstarošanās spektroskopijafotohromais efektsElektronu paramagnētiskā rezonanseFizika

researchProduct

Radiācijas defektu pētījumi ar EPR metodi LiBaF3 kristālā

2004

Izpētīts ar rentgenu istabas temperatūrā apstarotā L i B a F 3 kristālā radīta defekta EPR spektrs. EPR spektrs sastāv no apmēram 35 ekvidistantām līnijām. Defekts ir nestabils Jienas gaismā, bet tumsā sabrūk dažu stundu laikā. Šīs līnijas magnētiskā lauka orientācijā mralēli [111] kristāla asij atrodas vienādos attālumos (ar soli 0,9 mT) ar intensitāšu sadalījumu tuvu binomiālajam. EPR spektru var aprakstīt kā nesapārota spina S = 1/2 hiper- >īkstruktūras (liss) mijiedarbību ar divām ekvivalentu kaimiņu kodolu spinu grupām: 2 Li kodoliem pirmajā grupā un 8 F kodoliem otrajā grupā. Šāds modelis atbilst F-tipa centram elektrons atrodas fluora vakancē) LiBaF3 kristālā. Līniju intensitāšu stip…

LiBaF3 kristāliLiBaF3 crystalsCietvielu fizika:NATURAL SCIENCES::Physics::Atomic and molecular physics [Research Subject Categories]Elektronu paramagnētiskā rezonanseRadiācijas defektiElektronu spinu rezonanseElectron paramagnetic resonanceEPR spektroskopijaRadiation defectsElectron paramagnetic resonance spectroscopy

researchProduct

PEPhysical Sciences and Engineering
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